Friday, 30 December 2011

Ladle Metallurgy


Special treatment of melts:
1)      Before pouring molten metals are given certain treatment in order to purify them or alter the metallographic structure of castings.
2)      Such treatment is preformed either by plunging reagents into the furnace bath / ladle or by injecting etc.
3)      Various melt treatment are listed below:
a)      Refining (oxidation, deoxidation, degassing and desulphurisation)
b)      Inoculation (grain and constituents refinement, eutectic modification)

Refining:
            Refining is the process of removing unwanted impurities from the molten metal during its preparation for pouring into the molds.

Degassing:
a)      Vacuum degassing
-          Static bath treatment
-          Induction degassing
-          Fractional degassing
-          Stream droplet degassing
b)      Gas scavenging
-          Solid degasser
-          Jet degasser

Some of the alloys and scavenging gases employed:
1)      Copper base                            N2
2)      Aluminum base                       N2, Cl2, Ar
3)      Magnesium base                      Cl2, Ar
4)      Nickel base                              O2

Desulphurization:
-          Desulphurization means reducing the amount of sulphur.
-          Is carried out in ferrous alloys.
-          Typical desulphurization reagents are, for
Cast iron…………..soda ash, calcium carbide
Steel………………soda ash

Inoculation:
a)      An inoculation is an addition made to molten metal, usually late in the melting operation, for modifying the solidification structure and properties of the cast metals or alloys.
b)      Some common inoculation treatments are:
1)      Grain and constituents refinements
Alloys                                                typical inoculation
a)      Steel                                        Al, Ti
b)      Aluminum base                       Ti, B, Nb, Zr
c)      Magnesium base                      C, Zr
d)     Mg- Al                                                C
2)      Refinement and eutectic modification
Alloys                                                typical inoculation
a)      Al-Si                                        Na
b)      Cast iron                                  Si, C
c)      Cast iron                                  Mg, Ce 

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